09/08/2013 09:48 EDT | Updated 09/08/2013 09:49 EDT

Reese Witherspoon TIFF 2013: 'Walk The Line' Star Goes Flirty Chic On The Red Carpet (PHOTOS)

All hail Reese Witherspoon, Queen of the TIFF 2013 red carpet!

America's other sweetheart (the original being Sandra Bullock, natch) hit up the Toronto Film Festival in style for the premiere of the Atom Egoyan-directed flick, "Devil’s Knot" on Sunday night.

The 37-year-old flaunted her toned bod in a knee-length black and white frock which featured a diamond cutout neckline. Witherspoon accentuated the look with key lime green pumps and side-swept hair. Gorgeous!

This isn't Ryan Phillippe's ex's first time at TIFF; the "Legally Blonde" star made quite the impression when she promoted her film "Walk the Line" with Joaquin Phoenix in 2005. She would eventually earn a Best Actress Oscar for her role as June Cash.

Will Mrs. Jim Toth have her chance at a second golden statuette? Academy Award nominations are still months away, but it would be great to see our favourite blond rock the red carpet again in one of her many gorgeous gowns.

Reese is in a lot of good-looking company:

Photo gallery TIFF 2013 Red Carpet See Gallery