09/14/2013 08:12 EDT | Updated 09/14/2013 08:29 EDT

Jennifer Aniston TIFF 2013: Brad Pitt's Ex Is Worth The Wait At 'Life Of Crime' Red Carpet (PHOTOS)

TORONTO, ON - SEPTEMBER 14: Actress/producer Jennifer Aniston arrives at the 'Life Of Crime' Premiere during the 2013 Toronto International Film Festival at Roy Thomson Hall on September 14, 2013 in Toronto, Canada. (Photo by George Pimentel/WireImage)

Leave it to Jennifer Aniston to steal the show at TIFF 2013.

The former "Friends" star hit up the closing night of the Toronto Film Festival for the red carpet premiere of her film "Life of Crime" on Saturday.

Aniston, who was wearing a strapless dove grey Vivienne Westwood gown, told Ben Mulroney on ETalk that she felt "excited" to be closing the festival.

"I feel honoured especially because I'm so proud of this movie," the California blond babe said.

Fans were screaming for the perpetually perky 44-year-old, who looked fantastic in the sexy dress which featured a v-neck with a gathered cowl, a draped-gathered waist and a tucked in hem.

The colour is a bit of a departure for the "We're the Millers" star who is known for wearing body-hugging leather dresses and nude frocks. Jen kept her ashy blond hair down and straight and sported a nude lip and dark-rimmed eyes. The whole look came together with nude pumps. Glad to see Jen pulled out all the stops for TIFF!

Earlier in the day, Aniston sported a cute black Chanel dress and strappy Saint Laurent heels at the "Life of Crime" press conference. Jen can do no wrong!

While fiance Justin Theroux didn't walk the red carpet with his beloved, he did join his wife-to-be at the "Life of Crime" cocktail reception at the Hudson Kitchen earlier in the day.

Funnily enough, that same restaurant hosted Jen's ex, Brad Pitt, only a week earlier!

Pitt was at TIFF last week, sans Angelina Jolie, for the premiere of the critically-lauded film "12 Years A Slave".

There goes our wish for a Jennifer-Brad reunion!

Jen's only one of dozens of gorgeous celebs at TIFF 2013:

Photo gallery TIFF 2013 Red Carpet See Gallery